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31.
Kirill F. Sheberstov Eduard Sistaré Guardiola Damien Jeannerat 《Magnetic resonance in chemistry : MRC》2020,58(5):376-389
The fundamental concept of phase discussed in this tutorial aimed at providing students with an explanation of the delays and processing parameters they may find in nuclear magnetic resonance (NMR) pulse programs. We consider the phase of radio-frequency pulses, receiver, and magnetization and how all these parameters are related to phases and offsets of signals in spectra. The impact of the off-resonance effect on the phase of the magnetization is discussed before presenting an overview of how adjustment of the time reference of the free induction decay avoids first-order correction of the phase of spectra. The main objective of this tutorial is to show how the relative phase of a pulse and the receiver can be used to change the reference frequency along direct and indirect dimensions of NMR experiments. Unusual of phase incrementation with non-90° angles will be illustrated on one- and two-dimensional NMR spectra. 相似文献
32.
Jun Xu Victor V. Terskikh Yueying Chu Anmin Zheng Yining Huang 《Magnetic resonance in chemistry : MRC》2020,58(11):1082-1090
Metal–organic frameworks (MOFs) are a class of important porous materials with many current and potential applications. Their applications almost always involve the interaction between host framework and guest species. Therefore, understanding of host–guest interaction in MOF systems is fundamentally important. Solid-state NMR spectroscopy is an excellent technique for investigating host–guest interaction as it provides information complementary to that obtained from X-ray diffraction. In this work, using MOF α-Mg3(HCOO)6 as an example, we demonstrated that 13C chemical shift tensor of organic linker can be utilized to probe the host–guest interaction in MOFs. Obtaining 13C chemical shift tensor components (δ11, δ22, and δ33, where δ11 ≥ δ22 ≥ δ33) in this MOF is particularly challenging as there are six coordinatively equivalent but crystallographically non-equivalent carbons in the unit cell with very similar local coordination environment. Two-dimensional magic-angle-turning experiments were employed to measure the 13C chemical shift tensors of each individual crystallographically non-equivalent carbon in three microporous α-Mg3(HCOO)6 samples with different guest species. The results indicate that the δ22 component (with its direction approximately being co-planar with the formate anion and perpendicular to the C−H bond) is more sensitive to the adsorbate molecules inside the MOF channel due to the weak C−H···O hydrogen bonding or the ring current effect of benzene. The 13C isotropic chemical shift, on the other hand, seems much less sensitive to the subtle changes in the local environment around formate linker induced by adsorption. The approach described in this study may be used in future studies on host–guest interaction within MOFs. 相似文献
33.
Leah B. Casabianca 《Magnetic resonance in chemistry : MRC》2020,58(7):611-624
The nuclear magnetic resonance (NMR) chemical shift is extremely sensitive to molecular geometry, hydrogen bonding, solvent, temperature, pH, and concentration. Calculated magnetic shielding constants, converted to chemical shifts, can be valuable aids in NMR peak assignment and can also give detailed information about molecular geometry and intermolecular effects. Calculating chemical shifts in solution is complicated by the need to include solvent effects and conformational averaging. Here, we review the current state of NMR chemical shift calculations in solution, beginning with an introduction to the theory of calculating magnetic shielding in general, then covering methods for inclusion of solvent effects and conformational averaging, and finally discussing examples of applications using calculated chemical shifts to gain detailed structural information. 相似文献
34.
Tahya Bamine Edouard Boivin Christian Masquelier Laurence Croguennec Elodie Salager Dany Carlier 《Magnetic resonance in chemistry : MRC》2020,58(11):1109-1117
7Li, 31P, and 19F solid-state nuclear magnetic resonance (NMR) spectroscopy was used to investigate the local arrangement of oxygen and fluorine in LiVPO4F1-yOy materials, interesting as positive electrode materials for Li-ion batteries. From the evolution of the 1D spectra versus y, 2D 7Li radiofrequency-driven recoupling (RFDR) experiments combined, and a tentative signal assignment based on density functional theory (DFT) calculations, it appears that F and O are not randomly dispersed on the bridging X position between two X–VO4–X octahedra (X = O or F) but tend to segregate at a local scale. Using DFT calculations, we analyzed the impact of the different local environments on the local electronic structure. Depending on the nature of the VO4X2 environments, vanadium ions are either in the +III or in the +IV oxidation state and can exhibit different distributions of their unpaired electron(s) on the d orbitals. Based on those different local electronic structures and on the computed Fermi contact shifts, we discuss the impact on the spin transfer mechanism on adjacent nuclei and propose tentative signal assignments. The O/F clustering tendency is discussed in relation with the formation of short VIVO vanadyl bonds with a very specific electronic structure and possible cooperative effect along the chain. 相似文献
35.
Effect of thickness variations of lithium niobate on insulator waveguide on the frequency spectrum of spontaneous parametric down-conversion 下载免费PDF全文
Guang-Tai Xue 《中国物理 B》2021,30(11):110313-110313
We study the effect of waveguide thickness variations on the frequency spectrum of spontaneous parametric down-conversion in the periodically-poled lithium niobate on insulator (LNOI) waveguide. We analyze several variation models and our simulation results show that thickness variations in several nanometers can induce distinct effects on the central peak of the spectrum, such as narrowing, broadening, and splitting. We also prove that the effects of positive and negative variations can be canceled and thus lead to a variation-robust feature and an ultra-broad bandwidth. Our study may promote the development of on-chip photon sources in the LNOI platform, as well as opens up a way to engineer photon frequency state. 相似文献
36.
本文设计了一种由硅橡胶包覆层包裹4个钨振子的新型声子晶体结构,通过有限元法计算该结构的色散曲线、振动模态和传输损失谱。结果表明,该结构的带隙范围为18.85~225.28 Hz,与传输损失谱频率衰减范围相吻合,能够有效抑制20~200 Hz的弹性波在声子晶体中传播。通过分析色散曲线上点的振动模态,说明带隙产生的原因。本文讨论了声子晶体板的缺口角度和振子之间的纵向和横向间距对带隙的影响,结果表明:当缺口角度减小时,带隙下边界几乎保持不变,带隙上边界升高从而增加了带隙的宽度;振子之间横向或纵向间距增大时,带隙下边界和上边界均上升,带隙变宽,进而优化了声子晶体模型的带隙。同时声子晶体板的缺口设计能够节省材料,从而减轻结构的质量。 相似文献
37.
Shuo-Qing Liu 《中国物理 B》2022,31(7):74101-074101
We establish the beam models of Goos-Hänchen (GH) and Imbert-Fedorov (IF) effects in tilted Weyl semimetals (WSMs), and systematically study the influences of Weyl cone tilting and chemical potential on the GH and IF shifts at a certain photon energy 1.96 eV. It is found that the GH and IF shifts in tilted type-I and type-Ⅱ WSMs are both almost symmetric about the Weyl cone tilting. Meanwhile, the GH and IF shifts in type-I WSMs almost do not change with the tilt degree of Weyl cones, while those in type-Ⅱ WSMs are extremely dependent on tilt degree. These trends are mainly due to the nearly symmetric distribution of WSMs conductivities, where the conductivities keep stable in type-I WSMs and gradually decrease with tilt degree in type-Ⅱ WSMs. By adjusting the chemical potential, the boundary between type-I and type-Ⅱ WSMs widens, and the dependence of the beam shifts on the tilt degree can be manipulated. Furthermore, by extending the relevant discussions to a wider frequency band, the peak fluctuation of GH shifts and the decrease of IF shifts occur gradually as the frequency increases, and the performance of beam shifts at photon energy 1.96 eV is equally suitable for other photon frequencies. The above findings provide a new reference for revisiting the beam shifts in tilted WSMs and determining the types of WSMs. 相似文献
38.
在地球中传播的地震波主要有体波和表面波,而表面波中Rayleigh波对建筑物造成的破坏最为强烈。针对Rayleigh波的振动控制,提出一种田字形超材料结构。相比于传统的地震超材料,这种超材料屏障是由外部口字形框体内部嵌套十字形柱体组成,形成4个可填充区域,其外部框体采用部分埋入的方式,具有高强度、强稳定性、填充方式灵活的特点。应用有限元法计算了田字形超材料的能带结构和传输特性,并通过分析带隙边界处模态振型可知,带隙的打开是由于柱体的局域共振。结合带隙机理可知,柱体结构中土壤填充量不同可改变柱体的质量,形成不同的谐振频率,产生甚低频带隙。为进一步拓宽带隙,设计研究了正、负梯度的质量填充方式,均可得到3.3~13.1 Hz甚低频宽带隙,在谐振频率范围内两者的隔震方式分别为Rayleigh波彩虹捕获和Rayleigh波到体波的转化。最后,采用EI-Centro地震波对填充屏障进行了时程验证,加速度最大幅值衰减超过80%,为地震超材料在减震隔震方面应用提供了新的设计思路和方法。 相似文献
39.
Ying Wei Yuchen Zhang Jiahao Pan Tian Chen Dr. Xing Xing Prof. Weihua Zhang Prof. Zhenda Lu 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2023,135(2):e202214103
Plasmon-enhanced electrochemiluminescence (ECL) at the single-nanoparticle (NP) level was investigated by ECL microscopy. The Au NPs were assembled into an ordered array, providing a high-throughput platform that can easily locate each NP in sequential characterizations. A strong dependence of ECL intensity on Au NP configurations was observed. We demonstrate for the first time that at the single-particle level, the ECL of Ru(bpy)32+-TPrA was majorly quenched by small Au NPs (<40 nm), while enhanced by large Au ones (>80 nm) due to the localized surface plasmon resonance (LSPR). Notably, the ECL intensity was further increased by the coupling effect of neighboring Au NPs. Finite Difference Time Domain (FDTD) simulations conformed well with the experimental results. This plasmon enhanced ECL microscopy for arrayed single NPs provides a reliable tool for screening electrocatalytic activity at a single particle. 相似文献
40.
Xinliang Cai Yexuan Pu Prof. Chenglong Li Dr. Zhiheng Wang Prof. Yue Wang 《Angewandte Chemie (International ed. in English)》2023,62(27):e202304104
Multi-resonance thermally activated delayed fluorescence (MR-TADF) materials are considered a class of organic materials with exceptional electronic and optical properties, which make them promising for the applications in organic light-emitting diodes (OLEDs). In this study, we improved, synthesized, and characterized a multiple-resonance type emitter based on the assembly of MR-building blocks (MR-BBs). By optimizing the geometric arrangement of MR-BBs, we were able to generate narrowband emission in the longer wavelength region and shorten the delayed excited-state lifetime, resulting in improved emission efficiency compared to the parent molecule. Our proof-of-concept molecule, m-DBCz, exhibited narrowband yellowish-green TADF emission with a full width at half-maximum of 32 nm and a small singlet-triplet energy gap of 0.04 eV. The OLED developed using m-DBCz as the emitter demonstrated electroluminescence at 548 nm and achieved a high external quantum efficiency (EQE) of 34.9 %. Further optimization of the device resulted in a high external quantum efficiency of 36.3 % and extremely low efficiency roll-off, with EQE values of 30.1 % and 27.7 % obtained even at high luminance levels of 50 000 and 100 000 cd m−2. These results demonstrate the full potential of MR-TADF materials for applications on ultrahigh-luminance OLEDs. 相似文献